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Sunday, May 22, 2022 at 11:30:00 PM UTC

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Publisher Rating 7
Nanoscience
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Nanoscale Fabrication of Graphene by Hydrogen-Plasma Etching

Takamoto Yokosawa Masahiro Kamada Taisuke Ochi Yuki Koga
Acknolowdgement NA

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Graphene, Hydrogen-plasma etching, Atomic force microscopy, Raman spectroscopy

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Abstract
Graphene is attracting vast interest due to its superior electronic and mechanical properties. However, the structure and electronic properties of its edge are often neglected, although they are important for nanoscale devices because the edge ratio becomes larger by decreasing the device size. In this study, we suggest a way to fabricate graphene with atomically aligned zigzag edges by applying the hydrogen-plasma etching (HPE) technique. By patterning graphene prior to HPE, it succeeded to shape graphene in desired structure. Both atomic force microscopy and Raman spectroscopy con rm that the graphene shaped by this technique preserves its honeycomb structure even on the edge, which is aligned with the zigzag structure. Although the mechanism of the anisotropic etching by hydrogen-plasma has not been clari ed yet, the sample position dependence of the etching rate suggests that the hydrogen radicals are responsible for the anisotropic etching.